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Section 2.3

Thermodynamics

Temperature, heat, specific and latent heat, heat transfer, expansion and the gas laws.

Notes

Thermodynamics, summary notes

Main ideas
  • Temperature is the average kinetic energy of particles; heat is energy in transit between bodies at different temperatures.
  • Heat transfer happens three ways: conduction (through solids), convection (through fluids), radiation (no medium needed, how the sun heats a parked aircraft's skin).
  • First law: energy is conserved, change in internal energy equals heat added minus work done (ΔU = Q − W).
  • Second law: heat flows spontaneously from hot to cold, never the reverse without external work, why no heat engine, including a jet engine, can be 100% efficient.
  • Gas laws describe how pressure, volume and temperature relate for a fixed amount of gas, relevant to gas turbine cycles, tyre inflation with temperature and oxygen bottle behaviour at altitude.
Key formulas
Boyle's Law (constant T)
P₁V₁ = P₂V₂
Charles's Law (constant P)
V₁/T₁ = V₂/T₂
Gay-Lussac's Law (constant V)
P₁/T₁ = P₂/T₂
Combined/ideal gas law
P₁V₁/T₁ = P₂V₂/T₂
Heat energy
Q = mcΔT
Latent heat
Q = mL
First law
ΔU = Q − W
Temperature conversion
K = °C + 273 · °F = (°C × 9/5) + 32
Solved examples
  1. A gas cylinder holds 2 m³ at 100 kPa and constant temperature. It's compressed to 1 m³. Find the new pressure.

    Boyle's Law: P₂ = P₁V₁/V₂ = (100 × 2)/1 = 200 kPa.

  2. How much heat is needed to raise 5 kg of aluminium (specific heat capacity 900 J/kg·K) from 20°C to 80°C?

    Q = mcΔT = 5 × 900 × (80 − 20) = 270,000 J (270 kJ).

Simulation

Gas laws (PV = nRT)

Gas Laws, PV = nRTFull screen ↗
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Simulation

Heat transfer

Heat TransferFull screen ↗
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Simulation

Specific & latent heat

Specific & Latent HeatFull screen ↗
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Simulation

Thermal expansion

Thermal ExpansionFull screen ↗
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Mind map

Thermodynamics concept map

Thermodynamics

Quiz

Thermodynamics quiz

Thermodynamics

Ref 2.315 of 53Pass 75%
  1. 1. How much heat is needed to raise 2 kg of water by 30 K, taking the specific heat capacity as 4200 J/kg·K?

    252 kJ
    126 kJ
    8.4 kJ
  2. 2. A temperature of 27 °C expressed in kelvin is:

    300 K
    246 K
    27 K
  3. 3. A steel bar 10 m long is heated through 50 K. Taking the coefficient of linear expansion as 12 × 10⁻⁶ per K, the expansion is:

    6 mm
    60 mm
    0.6 mm
  4. 4. The SI unit of temperature is the:

    Kelvin
    Celsius
    Joule
  5. 5. 0 °C expressed in kelvin is:

    273 K
    0 K
    373 K
  6. 6. Heat is a form of:

    Energy
    Force
    Mass
  7. 7. The SI unit of heat energy is the:

    Joule
    Newton
    Watt
  8. 8. Specific heat capacity is the energy to raise ___ of a substance by 1 K.

    1 kg
    1 m³
    1 litre
  9. 9. Latent heat is absorbed or released during a:

    Change of state
    Temperature rise only
    Chemical reaction only
  10. 10. Latent heat of fusion relates to the change between:

    Solid and liquid
    Liquid and gas
    Gas and solid
  11. 11. Latent heat of vaporisation relates to the change between:

    Liquid and gas
    Solid and liquid
    Solid and gas
  12. 12. During a change of state, the temperature:

    Stays constant
    Rises
    Falls
  13. 13. Heat transfer through a solid is mainly by:

    Conduction
    Convection
    Radiation
  14. 14. Heat transfer in fluids by bulk movement is:

    Convection
    Conduction
    Radiation
  15. 15. Heat transfer that needs no medium is:

    Radiation
    Conduction
    Convection